Inorganic/organic hybrids of ZnO nanorods (NRs)/bisindolo quinoxaline (BIQ) were fabricated for broadband photosensing applications.Multiple material characterizations revealed the BIQ was self-assembled in a regular form of rod-like domain and bar drain board an irregular form of amorphous aggregation that were distributed on the ZnO NRs.Optical measurements showed that BIQ can absorb visible light with a wavelength up to 630 nm and effectively generate house of lashes blessings photoelectrons.Moreover, clustering of BIQ can be observed via the 3D optical microscopy.ZnO/BIQ hybrids were promising for future UV and visible light environmental monitoring applications.